The crystal structure of a molecular complex of acetylacetone with MnBr2 has been determined by an X-ray diffraction analysis: the manganese and bromine atoms constitute an infinite chain (MnBr2)∞ and two enolic acetylacetone molecules are linked to each metal atom as unidentate ligands, thus constructing the octahedral arrangement of [MnBr4O2].
S. Koda, S. Ooi, H. Kuroya, Y. Nakamura and S. Kawaguchi, J. Chem. Soc. D, 1971, 280 DOI: 10.1039/C29710000280
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