The nuclear quadrupole resonance spectra of some tetrahedral and square-planar nickel(II) complexes are reported: it is shown that the π-bonding character of the metal–halogen bond is ca. 10%.
P. W. Smith and R. Stoessiger, J. Chem. Soc. D, 1971, 279 DOI: 10.1039/C29710000279
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