SCHEDULED MAINTENANCE
Some unhindered alkyl-substituted cyclohexanones are reduced by phosphorous acid in aqueous propan-2-ol solution containing a catalyst prepared in situ from iridium chloride and phosphorous acid (or an easily hydrolysed ester of this acid) to give exceptionally high proportions (often >96%) of axial alcohols.
H. B. Henbest and T. R. B. Mitchell, J. Chem. Soc. C, 1970, 785 DOI: 10.1039/J39700000785
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