Issue 0, 1970
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Metal derivatives of hexafluoroisopropyl alcohol and related compounds

T. Blackmore,   M. I. Bruce,   P. J. Davidson,   M. Z. Iqbal  and  F. G. A. Stone  

Abstract

Hexafluoroacetone reacts with [(π-C5H5)Fe(CO)2]– to give (CF3)2C(OH)Fe(CO)2(π-C5H5). Hexafluoroacetylacetone (hfacH) cleaves both the carbonyl groups and the cyclopentadienyl ring from [(π-C5H5)Fe(CO)2]2 to give Fe(hfac)2. Reactions of sodium hexafluoroisopropoxide with (π-C5H5)2TiCl2, cis-(Ph3P)2PtCl2, and (Et3P)2NiCl2 give the corresponding hexafluoroisopropoxides. Sodium pentafluorophenoxide reacts more slowly with titanocene dichloride to give (π-C5H5)2Ti(OC6F5)Cl. Other related reactions are discussed.

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Article information

DOI
https://doi.org/10.1039/J19700003153
Article type
Paper

J. Chem. Soc. A, 1970, 3153-3158

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Metal derivatives of hexafluoroisopropyl alcohol and related compounds

T. Blackmore, M. I. Bruce, P. J. Davidson, M. Z. Iqbal and F. G. A. Stone, J. Chem. Soc. A, 1970, 3153 DOI: 10.1039/J19700003153

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