The 1H n.m.r. spectra indicate that hydrogen–deuterium exchange occurs between silicon and boron sites in silylphosphine–borane but not between carbon and boron sites in methylphosphine–borane. Condensation of monosilylphosphine to trisilylphosphine can be catalysed by diborane.
J. Davis, J. E. Drake and N. Goddard, J. Chem. Soc. A, 1970, 2962 DOI: 10.1039/J19700002962
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