Phosphorus trifluoride reacts with primary amines, RNH2, (R = Me, Et, Bun, or But) to give (alkylamino) difluorophosphines, RNH·PF2(R = Me, Et, Bun, or But), bis (alkylamino)difluorophosphoranes, (RNH)2·PF2H (R = Me, Et, or Bun), and bis(alkylamino) fluorophines, (RNH)2·PF(R = But).
J. S. Harman and D. W. A. Sharp, J. Chem. Soc. A, 1970, 1935 DOI: 10.1039/J19700001935
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