Thirteen chlorosilanes have been prepared by the reaction between phosphorus pentachloride and the corresponding silanes. Yields were between 78·1 and 96·4%. Silicon atoms bearing chlorine or oxygen atoms were less reactive than other silanes. Phenyldichlorosilane failed to react.
S. Mawaziny, J. Chem. Soc. A, 1970, 1641 DOI: 10.1039/J19700001641
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