The reactions between phosphorus pentafluoride and monoalkylamines are complex and yield adducts, alkylammonium hexafluorophosphates, alkylaminotetrafluorophosphoranes, and bis(alkylamino)trifluorophosphoranes under the appropriate conditions. A possible sequence of reactions is discussed.
J. S. Harman and D. W. A. Sharp, J. Chem. Soc. A, 1970, 1138 DOI: 10.1039/J19700001138
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