Kinetic isotope effects, kH/kD, of ca. 1·2 observed in the protonation of carbanions formed in phosphonium salt hydrolysis show that these carbanions are not free in the rate-determining transition state.
J. R. Corfield and S. Trippett, J. Chem. Soc. D, 1970, 1267a DOI: 10.1039/C2970001267A
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