Issue 20, 1970

The addition of dichloroketen to methylenecyclobutane: a new route to spiro[3,3]heptanes and spiro[3,2]hexanes

Abstract

In the addition of dichloroketen to methylene-cyclobutane, no non-classical ionic intermediates have been detected: a spiro[3,3]heptanone is obtained which can be reduced and ring-contracted, giving spiro[2,3]-hexane derivatives.

Article information

Article type
Paper

J. Chem. Soc. D, 1970, 1344-1345

The addition of dichloroketen to methylenecyclobutane: a new route to spiro[3,3]heptanes and spiro[3,2]hexanes

P. R. Brook and J. G. Griffiths, J. Chem. Soc. D, 1970, 1344 DOI: 10.1039/C29700001344

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