Di-t-butyl peroxide-catalysed reaction of pentamethyldisilane with pentamethyldisilanylacetylene afforded cis- and trans-bis(pentamethyldisilanyl)ethylene and bis(pentamethyldislanyl)acetylene, the latter being formed by a novel hydrogen-abstraction process from an intermediate vinyl radical.
H. Sakurai and M. Yamagata, J. Chem. Soc. D, 1970, 1144 DOI: 10.1039/C29700001144
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