The heterocyclic ring of 2,5-diphenyl-1,4-dithiin 1-oxide is arranged in a boat structure (X-ray), the oxygen atom being axial and the sulphoxide group differing in bond distances from the sulphide group.
G. Bandoli, D. A. Clemente, C. Panattoni, A. Dondoni and A. Mangini, J. Chem. Soc. D, 1970, 1143 DOI: 10.1039/C29700001143
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