Niobium pentafluoride forms with antimony pentafluoride a 1 : 1 adduct, the structure of which has been shown to be an endless chain arrangement, with a major contribution from the ionic form [NbF4]+[SbF6]–.
A. J. Edwards, J. Chem. Soc. D, 1970, 820 DOI: 10.1039/C29700000820
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