Issue 8, 1970

Evidence for a “foiled methylene” in the reactions of bicyclo[3,3,1]non-2-en-9-ylidene

Abstract

The carbene (1) reacts intramolecularly in a way strongly suggestive of preliminary interaction with the double bond; and, although cyclopropane formation is prevented by geometric factors, the “foiled methylene” determines the ultimate products.

Article information

Article type
Paper

J. Chem. Soc. D, 1970, 503-504

Evidence for a “foiled methylene” in the reactions of bicyclo[3,3,1]non-2-en-9-ylidene

M. H. Fisch and H. D. Pierce, J. Chem. Soc. D, 1970, 503 DOI: 10.1039/C29700000503

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