Tropyl azide (I) can be decomposed to form tropone-imonium azide (III) and N-tropyltroponeimonium azide (II); attempts to convert either salt or the corresponding fluoborates into tropone 2,4-dinitrophenylhydrazone leads to the corresponding benzaldehyde derivative.
D. S. Wulfman, L. N. McCullagh and J. J. Ward, J. Chem. Soc. D, 1970, 220 DOI: 10.1039/C29700000220
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