Issue 19, 1969

High-resolution mass spectrometry. Part VI. A hydrogen rearrangement in the mass spectra of pyrazole oximes

Abstract

The mass spectra of a number of syn- and anti-1-phenylpyrazol-4-yl oximes have been studied.

syn- and anti-Paris where available gave identical mass spectra; although no Beckmann rearrangement occurred, a transfer of the oximino-hydrogen to the pyrazole nucleus with concommittant fission of the side chain was shown to take place.

Article information

Article type
Paper

J. Chem. Soc. C, 1969, 2497-2499

High-resolution mass spectrometry. Part VI. A hydrogen rearrangement in the mass spectra of pyrazole oximes

I. L. Finar and B. J. Millard, J. Chem. Soc. C, 1969, 2497 DOI: 10.1039/J39690002497

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