Polyacetylenes occur widely in the plant family Campanulaceae. From Campanula glomerata L. 9-(tetrahydropyran-2-yl)-nona-trans,trans-2,8-diene-4,6-diyn-1-ol and 9-(tetrahydropyran-2-yl)-non-trans-8-ene-4,6-diyn-1-ol have been isolated and their structures confirmed by synthesis.
R. K. Bentley, J. K. Jenkins, E. R. H. Jones and V. Thaller, J. Chem. Soc. C, 1969, 830 DOI: 10.1039/J39690000830
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