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An exploratory study is reported of the benzene-induced shifts in the n.m.r. spectra of a range of acetylated monosaccharides. The solvent-induced shifts have been shown to be configurationally dependent and certain trends can be traced. The new results are discussed in terms of a model involving ‘benzene–solute association.’
M. H. Freemantle and W. G. Overend, J. Chem. Soc. B, 1969, 547 DOI: 10.1039/J29690000547
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