The coupling constants 1JPH and 2JPF in bis(trifluoromethyl)phosphine show marked solvent-dependence which is linearly related to the solvent dependence of the 1H chemical shift.
R. Fields, M. Green and A. Jones, J. Chem. Soc. A, 1969, 2740 DOI: 10.1039/J19690002740
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