The title compound (I) was prepared by ammonolysis of Me3Si·N(SiMe2Cl)2 and characterised. It rearranges in the presence of acids or bases to give principally [Me3Si·NH·Si(Me2)·N·SiMe2]2(III). Hydrolysis gave [Me3Si·N·Si(Me2)·O·SiMe2]2(V). Cyclodisilazanes are opened by methyl-lithium.
R. P. Bush and C. A. Pearce, J. Chem. Soc. A, 1969, 808 DOI: 10.1039/J19690000808
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