The 1-(1-adamantyl)vinyl cations (II), generated in sulphuric acid either by addition of 1-adamantyl carbonium ions to acetylene or by protonation of 1-adamantylacetylenes (I), are transformed into mixtures of 1-adamantyl methyl ketones (III) and homoadamantan-4-ones (V).
K. Bott, J. Chem. Soc. D, 1969, 1349 DOI: 10.1039/C29690001349
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