Solvolytic cyclization of the unsaturated tricyclic toluene-p-sulphonate (IV) affords the atiseran-13-ol derivative (VI), which at higher temperature undergoes Wagner–Meerwein rearrangement to the hibaan-12-ol isomer (IX).
R. M. Coates and E. F. Bertram, J. Chem. Soc. D, 1969, 797 DOI: 10.1039/C29690000797
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