Reduction of ethyl-2-methyl-2-(4-nitrophenoxy)-propionate (3a) with lithium borohydride in diglyme led to rearrangement to give the nitrophenoxy-alcohol (8); the unrearranged nitrophenoxy-alcohol (4) was produced by diborane reduction of the acid (3b).
M. Harfenist and E. Thom, J. Chem. Soc. D, 1969, 730 DOI: 10.1039/C29690000730
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