The effect of substituents in p-substituted benzoyl chlorides in their reactions with metal chelates of β-diketones has been investigated. A nitro-group was shown to increase the amount of C-acylation, and a methoxy-group the amount of O-acylation. A mechanistic interpretation of these results is proposed.
H. D. Murdoch and D. C. Nonhebel, J. Chem. Soc. C, 1968, 2298 DOI: 10.1039/J39680002298
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