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Halogenation of hexa-acetylaucubin in acetic acid or alcohols gives halogenoacetoxy- or halogenoalkoxy-derivatives. The differences in stereochemistry between these are explained in terms of a pathway involving conformational inversion.
P. W. Le Quesne, J. Chem. Soc. C, 1968, 1661 DOI: 10.1039/J39680001661
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