An analysis has been made of the carbonyl stretching frequencies of complexes of formula RFM(CO)5(M = Mn or Re, and RF is a monodentate fluorocarbon radical). Force constants have been calculated, from which the possible occurrence of fluorocarbon–metal π-bonding in these compounds is indicated.
J. Dalton, I. Paul and F. G. A. Stone, J. Chem. Soc. A, 1968, 1212 DOI: 10.1039/J19680001212
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