The observed rate for the decarbonylation of n-valeraldehyde by tris(triphenylphosphine)chlororhodium(I), RhCl(PPh3)3, in dichloromethane solution at 20° is given by the equation: Rate =k1[RhCl(PPh3)3]+k2[RhCl(PPh3)3][C4H9CHO], where k1= 5·68 × 10–5 sec.–1 and k2= 1·81 × 10–4 l. mole–1 sec.–1.
M. C. Baird, C. J. Nyman and G. Wilkinson, J. Chem. Soc. A, 1968, 348 DOI: 10.1039/J19680000348
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