Issue 0, 1968
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Chemistry of the metal carbonyls. Part XLI. Synthesis of complexes with C6F5S or p-RS·C6F4(R = Me or Ph) groups as ligands

Joan Cooke,   M. Green  and  F. G. A. Stone  

Abstract

Pentafluorothiophenol, or in some instances dipentafluorophenyl disulphide, reacts with Fe3(CO)12, [π-C5H5Fe(CO)2]2, [π-C5H5]2Ni, [ClRh(CO)2]2, or [ClRh(C2H4)2]2 to give the compounds [C6F5SFe(CO)3]2, C6F5SFe(CO)2(π-C6H5), [CH6SNi(π-C5H5)]n, [C6F5SRh(CO)2]2, and [C6F5SRh(C2H4)2]2, respectively. Treatment of the nickel complex and the dicarbonylrhodium compound with triphenylphosphine affords the complexes C6F5SNi(PPh3)(π-C5H5) and C6F5SRh(CO)(PPh3)2.

The synthesis of the compounds p-MeSC6F4Re(CO)5 and p-RSC6F4Fe(CO)2(π-C5H5)(R = Me or Ph) is also reported.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/J19680000170
Article type
Paper

J. Chem. Soc. A, 1968, 170-173

Permissions

Request permissions

Chemistry of the metal carbonyls. Part XLI. Synthesis of complexes with C6F5S or p-RS·C6F4(R = Me or Ph) groups as ligands

J. Cooke, M. Green and F. G. A. Stone, J. Chem. Soc. A, 1968, 170 DOI: 10.1039/J19680000170

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements