Pressure-composition isotherms have been derived from relationships obtained between electrode potential and hydrogen content for a series of Pd+Ag alloys at 25°C. For contents exceeding ca. 30 % Ag, the isotherms are supercritical in form with respect to regions of α- and β-phase coexistence; and confirm that the form of the relationship between hydrogen solubility and silver content is markedly dependent on the reference pressure.
A. W. Carson and F. A. Lewis, Trans. Faraday Soc., 1967, 63, 1453 DOI: 10.1039/TF9676301453
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