The cyclodepsipeptides produced by Pithomyces maydicus contain a major component, sporidesmolide IV, which has the structure cyclo-(L-α-hydroxyisovaleryl-D-valyl-D-leucyl-L-α-hydroxyisocaproyl-L-valyl-N-methyl-L-leucyl).
E. Bishop and D. W. Russell, J. Chem. Soc. C, 1967, 634 DOI: 10.1039/J39670000634
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