The chemical shifts of the NH-hydrogen in the conjugate acids of 1-substituted 4- and 5-nitroimidazoles depend on the relative position of the nitro-group. This method of orientation should be of general application.
J. S. G. Cox, C. Fitzmaurice, A. R. Katritzky and G. J. T. Tiddy, J. Chem. Soc. B, 1967, 1251 DOI: 10.1039/J29670001251
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