Issue 0, 1967

Polynuclear organoselenium derivatives of manganese and rhenium carbonyl

Abstract

Alkyl- and aryl-selenotin compounds react with pentacarbonyl halides of manganese and rhenium to produce the dimeric [M(CO)4SeR]2 species, in marked contrast to the corresponding reactions of tin–sulphur compounds, which produce the tricarbonyls [M(CO)3SR]n. Similar tricarbonyls [M(CO)3SeR]n, believed to contain a cluster of metal atoms, are obtained by pyrolysis of the tetracarbonyl species.

Article information

Article type
Paper

J. Chem. Soc. A, 1967, 2014-2017

Polynuclear organoselenium derivatives of manganese and rhenium carbonyl

E. W. Abel, B. C. Crosse and G. V. Hutson, J. Chem. Soc. A, 1967, 2014 DOI: 10.1039/J19670002014

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