The general problem of estimating parameters which occur non-linearly in a model representing experimental data arises in a variety of chemical problems and is discussed in relation to Mössbauer spectra. Various numerical methods, currently available, are discussed and compared. An overall strategy is outlined and the accuracy of the estimated parameters is considered.
B. J. Duke and T. C. Gibb, J. Chem. Soc. A, 1967, 1478 DOI: 10.1039/J19670001478
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