The vibrational spectrum of gallium trichloride under a variety of conditions is reported. Gas-phase infrared data and solid-state Raman data are included. The vibrational frequencies are assigned with the aid of a normal coordinate analysis, utilising a GVFF force constant for the bridge bonds which is less than one-half of that assumed for the terminal bonds.
I. R. Beattie, T. Gilson and P. Cocking, J. Chem. Soc. A, 1967, 702 DOI: 10.1039/J19670000702
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