The compound [Ir(SnCl3)(C8H12)2] has been shown by X-ray crystal analysis to contain five-co-ordinate iridium in a distorted trigonal bipyramidal environment of four double bonds and one tin atom. Reaction of this compound with (o-Ph2As·C6H4)3As, QAS, gives [Ir(SnCl3)(QAS)] which can be oxidised to [IrCl(SnCl3)(QAS)]Cl.
P. Porta, H. M. Powell, R. J. Mawby and L. M. Venanzi, J. Chem. Soc. A, 1967, 455 DOI: 10.1039/J19670000455
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