17α-Aminoandrostane derivatives have been prepared from 17β-alcohol tosylates either by direct inversion with secondary amines or via the intermediate 17α-azide and 17α-amine. Oxidation furnished corresponding saturated and unsaturated ketones.
M. Davis, E. W. Parnell and D. Warburton, J. Chem. Soc. C, 1966, 1698 DOI: 10.1039/J39660001698
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