Optically active derivatives of 7-oxodibenz[a,kl]anthracene substituted in the 13-position have been synthesised and their racemisation studied in solution. The Arrhenius parameters and transition-state theory functions for racemisation of these compounds are compared with those of some optically active members of the 1,1′-binaphthyl series, one of which is newly synthesised.
Y. Badar, A. S. Cooke and M. M. Harris, J. Chem. Soc. C, 1966, 1315 DOI: 10.1039/J39660001315
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