Diphosphonic tetrachlorides of general type Cl2PO(CH2)xPOCl2 were prepared and characterised, completing the series with x= 1–10. Periodicity of melting points of these substances was noted for the first time, this phenomenon being similar to that observed in several series of organic compounds devoid of phosphorus.
G. M. Kosolapoff and A. D. Brown, J. Chem. Soc. C, 1966, 757 DOI: 10.1039/J39660000757
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