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The benzylisoquinoline derivative, 4′,6-OO-dimethyl-laudanosoline [(±)-reticuline] has been synthesised in improved yield, and oxidised under mild aqueous conditions with ferricyanide at pH 6 to (±)-isoboldine in 5–6% yield. The relevance of this to biogenetic theory is discussed.
W. W. Chan and P. Maitland, J. Chem. Soc. C, 1966, 753 DOI: 10.1039/J39660000753
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