The catalytic decomposition of t-butyl hydroperoxide by a dialkyl diselenide and by alkane- and arene-seleninic anhydrides and acids in benzene at 75° into, solely, t-butyl alcohol and oxygen, is described. A free-radical mechanism is proposed.
D. T. Woodbridge, J. Chem. Soc. B, 1966, 50 DOI: 10.1039/J29660000050
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