Reaction of an excess of the halogen with the compound [C5H5Mo(CO)3]2 yields the derivatives C5H5Mo(CO)2X3(X = Cl, Br, or I), which are diamagnetic and non-electrolytes. Reaction of the tribromides with pyridine and 2,2-bipyridyl results in complete expulsion of carbon monoxide, to produce the impure compounds C5H5Mopy2Br3 and C5H5Mo bipyBr3, respectively.
R. J. Haines, R. S. Nyholm and M. H. B. Stiddard, J. Chem. Soc. A, 1966, 1606 DOI: 10.1039/J19660001606
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