Issue 0, 1966
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Triphenylgermylpalladium complexes

E. H. Brooks  and  F. Glockling  

Abstract

The complex (Et3P)2Pd(GePh3)2(II) decomposes at 97°, but is unstable in solution at –20°. The Ge–Pd bonds are cleaved by hydrogen chloride forming Ph3GeH and trans-(Et3P)2PdCl2, but when these products are heated together the palladium hydride, (Et3P)2Pd(H)Cl, is formed. The complex (II) reacts with 1,2-dibromoethane and also with hydrogen at 100 atm. and 20°. In the latter reaction only one Pd–Ge bond is cleaved, giving (Et3P)2Pd(H)GePh3. The anionic complex, K2[(CN)2Pd(GePh3)2] is obtained from complex (II) and KCN.

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Article information

DOI
https://doi.org/10.1039/J19660001241
Article type
Paper

J. Chem. Soc. A, 1966, 1241-1243

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Triphenylgermylpalladium complexes

E. H. Brooks and F. Glockling, J. Chem. Soc. A, 1966, 1241 DOI: 10.1039/J19660001241

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