Pentacarbonyl(hydrido)-manganese and -rhenium react with pentafluorobenzenethiol and benzenethiol to give the complexes C6F5S·M(CO)5(M = Mn or Re) and [RS·M(CO)4]2(M = Mn or Re; R = C6F5 or C6H5). By treating carbonyl(halogeno)-complexes of manganese and rhenium with thiols, a series of trimeric compounds [RS·M(CO)3]3(M = Mn or Re; R = C2H5 or n-C4H9, C6H5) has been obtained.
A. G. Osborne and F. G. A. Stone, J. Chem. Soc. A, 1966, 1143 DOI: 10.1039/J19660001143
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