Issue 0, 1966
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


The acid-catalysed reactions of transition-metal complexes. Part IV. The acid-catalysed aquations of cis- and trans-ammine- and isothiocyanato-nitrobisethylenediaminecobalt(III) salts

R. V. Bradley,   E. O. Greaves  and  P. J. Staples  

Abstract

The acid-catalysed replacement of the nitro-group from cis- and trans-[Co en2(NH3)NO2]2+ and [Co en2(SCN)NO2]+ salts has been studied in concentrated aqueous sulphuric and perchloric acids. The relationship between the rate of hydrolysis and the acid concentration suggests that the reactions proceed via a unimolecular mechanism.

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Article information

DOI
https://doi.org/10.1039/J19660000986
Article type
Paper

J. Chem. Soc. A, 1966, 986-988

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The acid-catalysed reactions of transition-metal complexes. Part IV. The acid-catalysed aquations of cis- and trans-ammine- and isothiocyanato-nitrobisethylenediaminecobalt(III) salts

R. V. Bradley, E. O. Greaves and P. J. Staples, J. Chem. Soc. A, 1966, 986 DOI: 10.1039/J19660000986

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