Issue 0, 1966
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Orthophosphato-complexes of the vanadyl(IV) ion in aqueous acidic solution. Part I. Ion-exchange studies

J. E. Salmon  and  D. Whyman  

Abstract

Complex formation in aqueous acidic vanadyl(IV) phosphate solutions has been studied by ion-exchange methods and may be represented by the equations VO2++ H2PO4–= VOHPO4+ H+, VOHPO4+ H2PO4–= HVO(HPO4)2–, HVO(HPO4)2–= VO(HPO4)22–+ H+.

A method is described by which the formula of a labile complex anion may be established from changes in ion concentrations observed in the solution phase when it is brought to equilibrium with anion-exchange resin.

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Article information

DOI
https://doi.org/10.1039/J19660000980
Article type
Paper

J. Chem. Soc. A, 1966, 980-985

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Orthophosphato-complexes of the vanadyl(IV) ion in aqueous acidic solution. Part I. Ion-exchange studies

J. E. Salmon and D. Whyman, J. Chem. Soc. A, 1966, 980 DOI: 10.1039/J19660000980

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