The stable liquid 1:1 complex formed between 1,1,2,2-tetrafluoroethylsilane and trimethylamine is the first of a new type of pentaco-ordinate silicon compound. Nuclear magnetic resonance and infrared spectroscopic data support this conclusion. Thermodynamic data are reported for the complex.
D. I. Cook, R. Fields, M. Green, R. N. Haszeldine, B. R. Iles, A. Jones and M. J. Newlands, J. Chem. Soc. A, 1966, 887 DOI: 10.1039/J19660000887
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