Themed collection #RSCPoster Twitter Conference
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Density functional theory predictions of the mechanical properties of crystalline materials
The DFT-predicted mechanical properties of crystalline materials are crucial knowledge for their screening, design, and exploitation.
CrystEngComm, 2021,23, 5697-5710
https://doi.org/10.1039/D1CE00453K
A promise to a sustainable future: 10 years of the Green Chemistry Commitment at Beyond Benign
The Green Chemistry Commitment (GCC) was founded in 2013 to host a community of practice around green chemistry in higher education. 10 years later, the GCC empowers a worldwide community to use chemistry tools to create a sustainable planet.
Green Chem., 2024,26, 6983-6993
https://doi.org/10.1039/D4GC00575A
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Reconsidering terms for mechanisms of polymer growth: the “step-growth” and “chain-growth” dilemma
Terms used for mechanisms of polymer growth are varied and problematic; we detail here our concerns with the terms “step-growth” and “chain-growth.” Ultimately, we seek terms that are simple, accurate, and attractive to the polymer community.
Polym. Chem., 2022,13, 2262-2270
https://doi.org/10.1039/D2PY00086E
Use of some cost-effective technologies for a routine clinical pathology laboratory
Cost-effective technologies allow >85% economical savings, making clinical pathology more accessible worldwide.
Lab Chip, 2021,21, 4330-4351
https://doi.org/10.1039/D1LC00658D
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Targeted modifications in ionic liquids – from understanding to design
The large number of possible ionic liquids makes fully empirical design virtually impossible. In this work, we show how targeted modifications can be and have been used to find the relevant structural features that define the properties of ionic liquids.
Phys. Chem. Chem. Phys., 2021,23, 6993-7021
https://doi.org/10.1039/D1CP00216C
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The Sea's best kept secret: the use of seaweed as a source of biohydrogen for clean and renewable energy
Seaweeds, or macroalgae, have been used for centuries as food additives, fertilizers, and in traditional medicines. Recent uses include energy (fuels) and as a source of bioactive compounds (vitamins and fucoidan).
RSC Sustain., 2024,2, 1289-1299
https://doi.org/10.1039/D3SU00381G
Harnessing molecular rotations in plastic crystals: a holistic view for crystal engineering of adaptive soft materials
This review highlights the exceptional properties of plastic crystals, their expanding scope in materials sciences and plenty of opportunities for designing new mechanically soft functional crystals.
Chem. Soc. Rev., 2020,49, 8878-8896
https://doi.org/10.1039/D0CS00475H
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Application of a differential technique in laser-induced fluorimetry/pulsed LED-fluorimetry: simple and reliable analysis of uranium raw materials in the nuclear fuel cycle – a mini-review
Application of differential technique is based on the comparison of the fluorescence of the standard with a sample of similar but unknown concentration on the same sample weight basis, by the use of H3PO4–NH4H2PO4 as a fluorescence-enhancing reagent.
Environ. Sci.: Adv., 2023,2, 1340-1350
https://doi.org/10.1039/D3VA00134B
Unveiling the bifunctional role of morphological differences of self-supported Cu(OH)2 in electrocatalysis
Structure engineering of copper foil by an anodization strategy for developing an electrocatalyst with nanoneedles showed exceptional MOR and OER activity.
J. Mater. Chem. A, 2023,11, 25854-25858
https://doi.org/10.1039/D3TA05471C
Probing the magnetic and magneto-optical properties of a radical-bridged Tb4 single-molecule magnet
The presence of the 1,2,4,5-tetrazinyl radical (tz˙−) in a tetranuclear TbIII metallocence leads to strong magnetic coupling and slow magnetic relaxation. Magneto-optical studies complete the spectroscopical profile of this magnetic unity.
Chem. Commun., 2023,59, 13970-13973
https://doi.org/10.1039/D3CC03034B
An electrochemical cascade process: synthesis of 3-selenylindoles from 2-alkynylanilines with diselenides
Herein, we present an efficient method for synthesizing 3-selenylindoles through an electrochemically driven oxidative cyclization of 2-alkynylanilines with diselenides under mild reaction conditions in an electrochemical undivided cell setup.
Chem. Commun., 2023,59, 8719-8722
https://doi.org/10.1039/D3CC02294C
Optochemical control of Cu(I) homeostasis in mammalian cells
A simple and efficient system for maintaining Cu(I) concentration spatiotemporally.
Chem. Commun., 2023,59, 2315-2318
https://doi.org/10.1039/D2CC05830H
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Synthesis of fluorescent carbon nanoparticles by dispersion polymerization of acetylene
Polymerization of acetylene using a Glaser-Hay dispersion polymerization was achieved, yielding spherical CNPs. UV irradiation of these CNPs makes them fluorescent in the blue region.
Nanoscale Adv., 2023,5, 337-343
https://doi.org/10.1039/D2NA00619G
Perovskite chemical gardens: highly fluorescent microtubes from self-assembly and ion exchange
We report the shape-preserving conversion of self-assembled CaCO3 microtubes to PbCO3 and MAPbBr3 perovskite.
Chem. Commun., 2022,58, 12736-12739
https://doi.org/10.1039/D2CC05611A
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Crystalline phosphino(silyl)carbenes that readily form transition metal complexes
We describe the synthesis of phosphino(silyl)carbenes bearing N-heterocyclic imine groups and show that these isolable, crystalline carbenes readily form stable copper(I) and gold(I) complexes.
Chem. Commun., 2022,58, 11831-11834
https://doi.org/10.1039/D2CC04321A
Regioselective access to di- and trisubstituted pyridines via a metal-oxidant-solvent-free domino reaction involving 3-chloropropiophenones
A metal-oxidant-solvent-free domino reaction of 3-chloropropiophenones, enolizable ketones and NH4OAc under an open atmosphere has been developed. This process generates a series of di- and trisubstituted pyridines regioselectively.
Org. Biomol. Chem., 2022,20, 6759-6765
https://doi.org/10.1039/D2OB01193J
A unique water soluble probe for measuring the cardiac marker homocysteine and its clinical validation
In this work, we describe a series of water soluble copper(II) compounds capable of selectively measuring the cardiac marker homocysteine in patients’ blood plasma via fluorescence technique.
Chem. Commun., 2022,58, 9210-9213
https://doi.org/10.1039/D2CC01515C
Rapid and sensitive naked eye detection of faecal pigments using their enhanced solid-state green fluorescence on a zinc acetate substrate
A cost-effective, nonhazardous, rapid and naked-eye detection approach for sensitive detection of faecal pigments using their enhanced solid-state green fluorescence on a zinc acetate substrate.
Anal. Methods, 2022,14, 2907-2912
https://doi.org/10.1039/D2AY00878E
Configurational ligand isomerism in conjoined-cages
Isomeric coordination complexes of different configurations (hour-glass and double-decker) but prepared from regioisomeric tridentate ligands are described.
Chem. Commun., 2022,58, 8480-8483
https://doi.org/10.1039/D2CC02837A
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Calix[6]arenes with halogen bond donor groups as selective and efficient anion transporters
A calix[6]arene with three preorganised halogen bond donating groups gives >100-fold selectivity for Cl− uniport over HCl symport, in contrast to analogous compounds with strong hydrogen bond donating groups.
Chem. Commun., 2022,58, 6255-6258
https://doi.org/10.1039/D2CC00847E
From PEF to rPEF: disclosing the potential of deep eutectic solvents in continuous de-/re-polymerization recycling of biobased polyesters
For the first time, the design of a urea : zinc acetate DES for a continuous, eco-friendly and closed-loop approach for recycling poly(ethylene 2,5-furandicarboxylate) (PEF) is communicated to avoid its future accumulation in the environment.
Green Chem., 2022,24, 3115-3119
https://doi.org/10.1039/D2GC00074A
Theoretical framework and experimental methodology to elucidate the supersaturation dynamics of nanocrystal growth
We developed theoretical and experimental methodology to characterize the supersaturation dynamics underlying nanocrystal growth. This can be used to identify supersaturation-associated shape evolutions, and predict growth profiles, of nanocrystals.
Nanoscale Horiz., 2022,7, 376-384
https://doi.org/10.1039/D1NH00572C
Substitution at sp3 boron of a six-membered NHC·BH3: convenient access to a dihydroxyborenium cation
6-SIDipp·BH3 (1) was reacted with I2 to give corresponding iodoboranes (2 & 3), which underwent nucleophilic substitution reactions to furnish OTf and ONO2 substituted boranes (4–7). Treatment of Br2/H2O with 1 led to a dihydroxyborenium cation (8).
Chem. Commun., 2022,58, 3783-3786
https://doi.org/10.1039/D1CC06816D
An electrochemical study on LiMn2O4 for Al3+ ion storage in aqueous electrolytes
An exclusive study on the Al3+ ion electrochemistry of LiMn2O4 in aqueous electrolytes is illustrated.
Phys. Chem. Chem. Phys., 2021,23, 19150-19154
https://doi.org/10.1039/D1CP03012D
Annulative Morita–Baylis–Hillman reaction to synthesise chiral dibenzocycloheptanes
The synthesis of racemic and chiral dibenzocycloheptanes has been achieved by employing the intramolecular Morita–Baylis–Hillman reaction as the key step.
Chem. Commun., 2021,57, 9260-9263
https://doi.org/10.1039/D1CC02765D
Self-assembled nickel cubanes as oxygen evolution catalysts
Ni4O4 cubanes [(μ3-L1O)NiCl(MeOH)]4 (1) and [(μ3-L2O)NiCl(H2O)]4 (2) (L1OH = 1-H-2-benzimidazolylmethanol, L2OH = 1-methyl-2-benzimidazolylmethanol) self-assemble, providing easy access to oxygen evolution electrocatalysts.
Chem. Commun., 2021,57, 8608-8611
https://doi.org/10.1039/D1CC03227E
Borane catalyzed polymerization and depolymerization reactions controlled by Lewis acidic strength
Triphenylborane catalyzes polyester-block-polycarbonate polymer formation from epoxides, anhydrides and carbon dioxide. Whereas, tris(pentafluorophenyl)borane selectively depolymerizes polycarbonate polymers and blocks.
Chem. Commun., 2021,57, 7320-7322
https://doi.org/10.1039/D1CC02218K
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Lewis base-free thiophosphonium ion: a cationic sulfur atom transfer reagent
A thiophosphonium ion was isolated in its free, monomeric form for the first time. The highly electrophilic species thionates carbonyl groups already at room temperature and undergoes phosphorus–chalcogen bond metathesis reactions with phosphine oxides, selenides and tellurides.
Chem. Commun., 2021,57, 5043-5046
https://doi.org/10.1039/D1CC01273H
Diverse reactivity of carbenes and silylenes towards fluoropyridines
The activation of the para C–F bond of C5F5N by IDipp led to functionalization of all three carbon atoms of the imidazole ring. When the para C–F bond is replaced with a C–H bond, IDipp activates the other C–F bonds leaving the C–H bond intact.
Chem. Commun., 2021,57, 4428-4431
https://doi.org/10.1039/D1CC01401C
Selective DCP detection with xanthene derivatives by carbonyl phosphorylation
Dual mode signalling for DCP detection with rhodamine-6G derivatives through phosphorylation at the spirocyclic carbonyl end.
Chem. Commun., 2020,56, 9308-9311
https://doi.org/10.1039/D0CC03985C
Computational discovery of promising new n-type dopable ABX Zintl thermoelectric materials
We develop a chemical replacements in structure prototype (CRISP) approach for novel materials discovery with functional applications.
Mater. Horiz., 2020,7, 1809-1818
https://doi.org/10.1039/D0MH00197J
Role of molecular bend angle and biaxiality in the stabilization of the twist-bend nematic phase
Within mean-field theory for V-shaped molecules, we have investigated how the alteration of a molecule's structural features influence the stabilization of modulated and non-modulated nematic phases.
Soft Matter, 2020,16, 4350-4357
https://doi.org/10.1039/D0SM00078G
Oxyanion transport across lipid bilayers: direct measurements in large and giant unilamellar vesicles
A simple, carbazole-based dithioamide receptor transports a variety of biologically relevant anions through lipid bilayers, as shown by direct fluorescent assays in LUVs and GUVs.
Chem. Commun., 2020,56, 4910-4913
https://doi.org/10.1039/C9CC09888G
Quantification of ion migration in CH3NH3PbI3 perovskite solar cells by transient capacitance measurements
We quantify activation energy, concentration, and diffusion coefficient of mobile ions in MAPbI3 perovskite solar cells using transient ion-drift measurements.
Mater. Horiz., 2019,6, 1497-1503
https://doi.org/10.1039/C9MH00445A
T and V-shaped donor–acceptor–donor molecules involving pyridoquinoxaline: large Stokes shift, environment-sensitive tunable emission and temperature-induced fluorochromism
The critical role of molecular shapes in the environment-sensitive and temperature-induced emission properties of pyridoquinoxaline-based donor–acceptor–donor molecules was demonstrated.
Chem. Commun., 2018,54, 1786-1789
https://doi.org/10.1039/C7CC09261J
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Photochemical halogen-bonding assisted generation of vinyl and sulfur-centered radicals: stereoselective catalyst-free C(sp2)–S bond forming reactions
Constructing alkenyl sulfides has never been so easy! A new halogen-bonding assisted photochemical transformation allows for the catalyst free cross-coupling between vinyl halides and thiols under basic conditions and visible light irradiation.
Chem. Sci., 2023,14, 650-657
https://doi.org/10.1039/D2SC05556B
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Fluorine extraction from organofluorine molecules to make fluorinated clusters in yttrium MOFs
The reaction of yttrium(III) and linker makes a 2D metal–organic framework. The addition of fluorinated modulators result in fluorine extraction from modulators and makes a 3D-MOF.
Chem. Sci., 2022,13, 14285-14291
https://doi.org/10.1039/D2SC05143E
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Room temperature chemoselective hydrogenation of C
C, C
O and C
N bonds by using a well-defined mixed donor Mn(I) pincer catalyst
Chemoselective hydrogenation of CC, C
O and C
N bonds in α,β-unsaturated ketones, aldehydes and imines is accomplished at room temperature (27 °C) using a well-defined Mn(I) catalyst and 5.0 bar H2.
Chem. Sci., 2022,13, 13764-13773
https://doi.org/10.1039/D2SC05274A
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Carrier gas triggered controlled biolistic delivery of DNA and protein therapeutics from metal–organic frameworks
We can alter the release kinetics of highly stabilized biomacromolecules in both skin and plant tissues to allow for either instant release or slow release simply by changing the typeof gas used in a pneumatic delivery jet.
Chem. Sci., 2022,13, 13803-13814
https://doi.org/10.1039/D2SC04982A
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Exploring the configurational space of amorphous graphene with machine-learned atomic energies
Machine-learning models for atomic energies can be used to drive Monte-Carlo structural exploration, and also to obtain new insight into disordered structures – as demonstrated here for amorphous graphene.
Chem. Sci., 2022,13, 13720-13731
https://doi.org/10.1039/D2SC04326B
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Towards new coordination modes of 1,2,3-triazolylidene: controlled by the nature of the 1st metalation in a heteroditopic bis-NHC ligand
The nature of the first metal coordination electronically influences the 1,2,3-triazolium moiety in [L2-H2]Br2, which leads to the unprecedented selective activation of triazole C4/C5 positions as supported by the isolation of several bimetallic complexes.
Chem. Sci., 2022,13, 13387-13392
https://doi.org/10.1039/D2SC05024B
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Total synthesis of the antibacterial polyketide natural product thailandamide lactone
A convergent strategy for the total synthesis of the structurally intriguing polyketide natural product thailandamide lactone has been developed for the first time. The antibacterial activity of the molecule has also been disclosed.
Chem. Sci., 2022,13, 13403-13408
https://doi.org/10.1039/D2SC04727F
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Thiazole fused S,N-heteroacene step-ladder polymeric semiconductors for organic transistors
Ladder-type thiazole-fused S,N-heteroacenes with an extended π-conjugation consisting of six (SN6-Tz) and nine (SN9-Tz) fused aromatic rings have been synthesized and fully characterized.
Chem. Sci., 2022,13, 12034-12044
https://doi.org/10.1039/D2SC04661J
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Perpetuating enzymatically induced spatiotemporal pH and catalytic heterogeneity of a hydrogel by nanoparticles
This work reports perpetuating effect in enzymatically generated spatiotemporal pH gradient across a hydrogel in presence of cationic gold nanoparticle; showing a new route in spatially resolved chemistry in a membrane-free environment.
Chem. Sci., 2022,13, 8557-8566
https://doi.org/10.1039/D2SC02317B
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Point mutations in SARS-CoV-2 variants induce long-range dynamical perturbations in neutralizing antibodies
Mutations in the new variants of SARS-CoV-2 spike protein modulates the dynamics of the neutralizing antibodies. Capturing such modulations from MD simulations and graph network model identifies the role of mutations in facilitating immune evasion.
Chem. Sci., 2022,13, 7224-7239
https://doi.org/10.1039/D2SC00534D
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Pressing matter: why are ionic liquids so viscous?
We use an experimental approach to compare an ionic liquid with a molecular mimic, focusing on viscosities. Charge network and coulombic compaction contribute significantly to the high viscosity of ionic liquids; we discuss the implications on their design and optimisation.
Chem. Sci., 2022,13, 2735-2743
https://doi.org/10.1039/D1SC06857A
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Spatiotemporal dynamics of self-assembled structures in enzymatically induced agonistic and antagonistic conditions
We have shown ATP-driven spatiotemporally distinct self-organization pattern of a surfactant in a two-dimensional space using enzymes, demonstrating a new route for obtaining ‘spatial’ organizational adaptability among interacting components.
Chem. Sci., 2022,13, 274-282
https://doi.org/10.1039/D1SC05353A
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Direct synthesis and applications of solid silylzinc reagents
The first direct synthesis of PhMe2SiZnI and Me3SiZnI reagents from silyl iodides is described. They can be obtained as solids and stored at 4 °C for extended periods. The versatility of solid Me3SiZnI is demonstrated in a variety of reactions.
Chem. Sci., 2021,12, 15719-15726
https://doi.org/10.1039/D1SC06038D
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Mg(II) heterodinuclear catalysts delivering carbon dioxide derived multi-block polymers
Carbon dioxide-based multiblock polymers are synthesised, in one-pot, from a mixture of monomers using a highly selective and active heterodinuclear Co(II)Mg(II) catalyst.
Chem. Sci., 2021,12, 12315-12325
https://doi.org/10.1039/D1SC03856G
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Dissipative operation of pH-responsive DNA-based nanodevices
We demonstrate here the use of 2-(4-chlorophenyl)-2-cyanopropanoic acid (CPA) and nitroacetic acid (NAA) as convenient chemical fuels to drive the dissipative operation of DNA-based nanodevices.
Chem. Sci., 2021,12, 11735-11739
https://doi.org/10.1039/D1SC03435A
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Effects of turn-structure on folding and entanglement in artificial molecular overhand knots
Spacers linking 2,6-pyridinedicarboxamide units influence the tightness of the corresponding lanthanide-coordinated overhand knot. β-Hairpin forming motifs generate a metal-coordinated pseudopeptide with a knotted tertiary structure.
Chem. Sci., 2021,12, 1826-1833
https://doi.org/10.1039/D0SC05897A
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Stability of radical-functionalized gold surfaces by self-assembly and on-surface chemistry
We have investigated the radical functionalization of gold with a derivative of the perchlorotriphenylmethyl radical using two methods: by chemisorption from the radical solution and by on surface chemical derivation from a precursor.
Chem. Sci., 2020,11, 9162-9172
https://doi.org/10.1039/D0SC03399E
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Conformational design concepts for anions in ionic liquids
Interchangeable functional groups for imide ions are investigated computationally, new ILs with low/high viscosity are designed a priori and experimentally characterised.
Chem. Sci., 2020,11, 6405-6422
https://doi.org/10.1039/D0SC01379J
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Evolutionary chemical space exploration for functional materials: computational organic semiconductor discovery
Evolutionary optimisation and crystal structure prediction are used to explore chemical space for molecular organic semiconductors.
Chem. Sci., 2020,11, 4922-4933
https://doi.org/10.1039/D0SC00554A
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Predicting retrosynthetic pathways using transformer-based models and a hyper-graph exploration strategy
We present an extension of our Molecular Transformer model combined with a hyper-graph exploration strategy for automatic retrosynthesis route planning without human intervention.
Chem. Sci., 2020,11, 3316-3325
https://doi.org/10.1039/C9SC05704H
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Insights into mechanochemical reactions at the molecular level: simulated indentations of aspirin and meloxicam crystals
Working towards a fundamental description of mechanochemical reactions through the use of classical molecular dynamics simulations. Capturing the transfer of molecules between two non-volatile molecular crystals during mechanochemical events.
Chem. Sci., 2019,10, 2924-2929
https://doi.org/10.1039/C8SC04971H
Harnessing halogen bond donors for enhanced nitrogen reduction: a case study on metal-free boron nitride single-atom catalysts
Catalyst design for NH3 synthesis is vital yet challenging. This study highlights the role of halogen bond donors as catalytic promoters, aiding activation of N2. This study offers insights for robust metal-free catalysts and promoters in NRR research.
Phys. Chem. Chem. Phys., 2024,26, 12495-12509
https://doi.org/10.1039/D4CP00076E
Augmentation of inductive effects through short range intramolecular hydrogen bonds for the improvement of cooperativity of trimeric rosettes
Three key design elements improve the binding strength of trimeric rosettes: the direction of hydrogen bonds, the addition of groups with inductive effects, and the presence of ambifunctional intramolecular hydrogen bonds between the substituents.
Mol. Syst. Des. Eng., 2024,9, 345-351
https://doi.org/10.1039/D4ME00008K
Validating superior electrochemical properties of Ti3C2 MXene for supercapacitor applications through first-principles calculations
This work investigates the performance of Ti3C2 MXene for supercapacitor applications and validated its efficacy as an electrode material utilizing first-principles calculations.
New J. Chem., 2024,48, 4982-4994
https://doi.org/10.1039/D3NJ05075K
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Transition metal incorporation: electrochemical, structure, and chemical composition effects on nickel oxyhydroxide oxygen-evolution electrocatalysts
Trace metal cations dissolved in alkaline electrolytes incorporate into nickel hydroxide/oxyhydroxide through in situ cation exchange, creating an interstratified structure near the surface of the material that impacts the electrochemical performance.
Energy Environ. Sci., 2024,17, 2028-2045
https://doi.org/10.1039/D3EE03617K
Stereoselective synthesis of thailandamide A methyl ester
A convergent route of total synthesis of structurally challenging polyene polyketide thailandamide A methyl ester has been achieved. Notably, a less explored Pd(I)-based Heck coupling has been introduced to couple two major segments quite efficiently.
Org. Biomol. Chem., 2024,22, 1409-1419
https://doi.org/10.1039/D3OB02107F
Biogenic carbon dots: a novel mechanistic approach to combat multidrug-resistant critical pathogens on the global priority list
This study delves into investigating alternative methodologies for anti-microbial therapy by focusing on the mechanistic assessment of carbon dots (CDs) synthesized from F. benghalensis L. extracts.
J. Mater. Chem. B, 2024,12, 202-221
https://doi.org/10.1039/D3TB02374E
Selective C–O bond cleavage in diphenyl ether via catalytic transfer hydrogenolysis over Ru-decorated nanocrystalline H-ZSM-5
Ru NPs incorporated nanocrystalline HZSM-5 selectively break C–O bonds in diphenyl ether, a lignin model compound, via a sustainable catalytic transfer hydrogenolysis pathway, transforming it into valuable fuels and fuel additives.
Sustainable Energy Fuels, 2023,7, 5714-5732
https://doi.org/10.1039/D3SE01285A
Eliminating waste with waste: transforming spent coffee grounds into microrobots for water treatment
Water pollutants such as oil spills, industrial dyes, and microplastics threaten public health and aquatic ecosystems.
Nanoscale, 2023,15, 17494-17507
https://doi.org/10.1039/D3NR03592A
Laser-irradiated carbonized polyaniline-N-doped graphene heterostructure improves the cyclability of on-chip microsupercapacitor
Laser irradiation technique has been employed to synthesize EDLC-type material N-doped carbonized graphene from pseudocapacitive polyaniline, which shows capacitive enhancement up to 135% after 70k continuous cycles.
Nanoscale, 2023,15, 15268-15278
https://doi.org/10.1039/D3NR02862C
Metal-free photocatalytic transformation of waste polystyrene into valuable chemicals: advancing sustainability through circular economy
Upcycling waste polystyrene into valuable chemicals acetophenone and benzoic acid is developed through an innovative and environmentally-friendly photocatalytic process involving a metal-free carbon catalyst.
Green Chem., 2023,25, 7318-7334
https://doi.org/10.1039/D3GC02591H
Histamine-bound magnesium porphyrins: diverse coordination modes, inhibitory role in photodegradation of chlorophyll a and antioxidant activity
The crystal structure of two histamine-bound magnesium porphyrins is reported which doesn't undergo photodegradation in the presence of oxygen and light. The histamine-bound complexes also have enhanced antioxidant activity.
Dalton Trans., 2023,52, 11085-11095
https://doi.org/10.1039/D3DT01309J
![Open Access](https://www.rsc-cdn.org/pubs-core/2022.0.148/content/NewImages/open-access-icon-orange.png)
Defect chemistry and ion transport in low-dimensional-networked Li-rich anti-perovskites as solid electrolytes for solid-state batteries
This work reveals the relationships between defects, Li-ion dynamics and dimensionality in anti-perovskite solid electrolytes. Significant increases in defect concentrations and ion transport are observed with decreasing dimensionality from 3D to 0D.
Energy Adv., 2023,2, 653-666
https://doi.org/10.1039/D3YA00075C
Mechanistic insights into the inhibition of amyloid-β aggregation by chitosan
Chitosan polysaccharides inhibit amyloid-β aggregation by sequestering peptides, and suppressing ultimate multimer sizes. Concentration and charge-density of chitosan chains influence peptide conformations and aggregate properties.
Phys. Chem. Chem. Phys., 2023,25, 10113-10120
https://doi.org/10.1039/D3CP00162H
Transformation of a copper-based metal–organic polyhedron into a mixed linker MOF for CO2 capture
Transformation of copper MOP-1 into a new mixed linker metal–organic framework CuMOF-Bipy.
Dalton Trans., 2023,52, 4415-4422
https://doi.org/10.1039/D2DT04162F
About this collection
The annual #RSCPoster LinkedIn Conference (https://rsc.li/poster) is our flagship celebration of science, drawing together researchers to network with peers, engage in scientific debate and share their research with the global chemistry community. Previously taking place on Twitter, the event now takes place for 24 hours on LinkedIn each year. Following feedback from participants, we are showcasing work from poster presenters in this collection to give a more permanent home to the research presented.
If you have participated in an #RSCPoster and would like to present your work in this collection, please see our survey at https://www.smartsurvey.co.uk/s/RSCPoster/. Please note that to be featured, your work must be published in a Royal Society of Chemistry journal; we cannot display articles at other publishers on this platform. We will be continuously updating the collection and adding articles as requested by presenters, so please return to this page to view the latest works from the #RSCPoster community.