Highly efficient grafting of hetero-complementary amidinium and carboxylate hydrogen-bonding/ionic pairs onto polymer surfaces†
Ana M.
Fernandes, 
a
Manuel C.
Martos-Maldonado,
a
Javier
Araujo-Morera,
a
Claudia
Solek
a
and
David
González-Rodríguez
*ab
a
Manuel C.
Martos-Maldonado,
a
Javier
Araujo-Morera,
a
Claudia
Solek
a
and
David
González-Rodríguez
*ab
Abstract
We describe a grafting methodology, based on thiol-fluoroarene chemistry, to efficiently incorporate complementary hydrogen-bonding carboxylate and amidinium groups into polymer backbones. The process was optimized both in solution and on the surface of processed films, with the aim to produce materials showing hetero-complementary adhesion.
- This article is part of the themed collection: ChemComm 60th Anniversary Board Member Collection
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