Oxygen atom transfer (OAT) from N2O to the Ni–H bond of proton-responsive picoline-derived CNP nickel complexes has been investigated both experimentally and theoretically. These Ni–CNP complexes efficiently catalyse the reduction of N2O with pinacolborane (HBpin) under mild conditions.
J. Bermejo, I. Ortega-Lepe, L. L. Santos, N. Rendón, J. López-Serrano, E. Álvarez and A. Suárez, Chem. Commun., 2024, 60, 1575 DOI: 10.1039/D3CC05455A
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