Issue 12, 1980

Solution calorimetry of nitrosonium salts

Abstract

The standard enthalpies of formation of crystalline [NO][ClO4], [NO][HSO4], and [NO]2[S2O7] have been determined as 59.0, –680.3, and –1 041.0 kJ mol–1 respectively, based on enthalpies of reaction with aqueous base. The discrepancies between these and some previously published values are discussed in terms of the competing neutralisation and disproportionation reactions of nitrous acid in aqueous medium.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1980, 2415-2417

Solution calorimetry of nitrosonium salts

A. Finch, P. N. Gates and T. H. Page, J. Chem. Soc., Dalton Trans., 1980, 2415 DOI: 10.1039/DT9800002415

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